活性炭吸附去除苯二胺

　　SHUIZAIHUANJINGBAOHUZHONGYIZHISHIGUANJIANWENTI，RANERYOUYUGONGYEHUODONGZHONGPAIFANGDEHUAXUEFEILIAO，WURANXIANXIANGYUELAIYUEDUO。ZHEXIEHUAXUEFEISHUIBAOHANDEWURANWUKEYISHIWUJIDE，LIRUZHONGJINSHU，YEKEYISHIYOUJIDE，BAOKUOYOUJIRANLIAO，LIRUZHUYAOYONGYUHUAZHUANGPINXINGYEDEDUIBENERAN。GAIHUAHEWUHUIDAOZHIHENDUOWENTI，MIANDUIZHEZHONGQINGKUANG，XIFUJISHUSHIQUCHUWURANWUYOUJISHUIZHONGJIANDAN，YOUXIAODEFANGFA。ERHUOXINGTANSHIBIJIAOCHANGYONGDEXIFUJI，BENCIWOMENCESHIYIXIAHUOXINGTANXIFUQUCHUBENERANDEJUTIXIAOGUO。

　　活性炭的制備條件

　　HUOXINGTANDEZHIBEIZAISHIWENXIAGANZAOZHIQIAN，YONGZHENGLIUSHUIXIDI，SUIHOUJINXINGFENSUIYANMOCHULIBINGSHIYONGDIANSHAISHAIFEN，YIHUODE63μmDEJUNYUNFENMOLIDU。SUODEFENMOZAISHIYONGDIANLUDUANSHAOQIANYONGLINSUANJINXINGHUAXUEYUCHULI。GENJUTEDINGBILITIANJIALINSUANLAIJINXINGHUOHUA，BINGZAI110℃DELUZHONGGANZAO48XIAOSHI。SUIHOUJIANGGANZAOHUNHEWUYINRUGANGUOTAOCIZHONG，ZAI450℃XIAZAILUZHONGDUANSHAO，SHIQIKONGXIZHUJIANDAKAI。YONGZHENGLIUSHUICHEDIQINGXIHUOXINGTANBIAOMIANDEHUOXINGCANLIUWU，GAIBUZOUYONGLAIKONGZHIHUOXINGTANDEpH。ZHEYANGDEDAODEHUOXINGTANZAI110℃DEHONGXIANGZHONGZAICIGANZAO48XIAOSHIHUODECHENGPIN。

　　活性炭的間歇吸附研究

　　HUOXINGTANDEXIFUSHIJIANYINGXIANGKECONGTU1KANCHU，HUOXINGTANXIFUFENSANBUJINXING：DIYISHIZAIZUICHUDE30FENZHONGNEI，WURANWUDEXIFULIANGHENKUAIJIUBEIQUEDINGLE，ZHEKEYIYONGZAIXIFUJIDEWAIBIAOMIANCUNZAIDALIANGKONGZHIDEJIEHEWEIDIAN，ZHESHIDEXIFUJIYIYUXIFUDAOGAIBIAOMIAN。DIERZAI31FENZHONGHOU，XIFUSULVJIANGDI，GUOCHENGHUANMAN。HUOXINGTANDEQITAWEIZHIDADAOBAOHEHOU，WURANWUKELIJIANGQIANYIDAOXIFUJINEIBU。YOUYUYIYUJIEJIN，YINCIXIFUGUOCHENGHUANMAN：KELINEIKUOSAN。DISANCONG80FENZHONGKAISHI，WOMENGUANCHADAOYICIJIECHU，HUOXINGTANYIDADAOQIZUIDARONGLIANG。WOMENKEYISHUOZHEXIEXIFUJIDEPINGHENGSHIJIANSHI80FENZHONG。RANER，LINSUANHUOHUADEHUOXINGTANXIFULIANGDEYANHUAQUXIANXIANSHI，ZAIZUICHUDE30FENZHONGNEI，WURANWUDEXIFULIANGXIANZHUZENGJIA，CIHOU，WURANWUDEXIFULIANGJIJUXIAJIANG，ZHEJIANGSHIYIZHONGCHANWUJIEXI。ZHEYIXIANXIANGZAIQITAXIFUJIZHONGSHIBUKEJIANDE，ZHEKENENGYIWEIZHUKEYONGKONGXIDESHULIANGHEJIEHELISUIZHUSUOYONGHUOHUAJINONGDUDEZENGJIAERZENGJIA，ZHEYIDIANHUANTONGGUODIANZHIHEYAJIAJILANDEZHIJINXINGLEYANZHENG。

　　TU1：JIECHUSHIJIANDUIZHIBEIDEHUOXINGTANSHANGBENERANXIFURONGLIANGDEYINGXIANG。

　　BENERANDECHUSHINONGDUDUIHUOXINGTANXIFUDEYINGXIANGZAITU2XIANSHILE，XIFUBAIFENBISUIRONGYECHUSHINONGDUDEZENGJIAERZENGJIA。ZHEKENENGSHIJIESHIWEINONGDUDEZENGJIADAOZHIZAIHUOXINGTANBIAOMIANFENZIWURANWUCHANSHENGLEYIGEDADECHUANDILI，ZAIHUOXINGTANBIAOMIANCUNZAIDEFENZISHULIANGZENGJIA，YINCICUJINXIFU。WOMENKEYIKANDAO，ZAIXIANGTONGDEBILIXIA，DINONGDUXIAHUOXINGTANDEXIFUBAIFENLVGAOYUCANZHAOXIFUJIDEXIFUBAIFENLV。ZHEKEYIDECHUJIELUN，HUOXINGTANBIAOMIANDEXIFUBUTAISHOUFASHENGDEQIANYIXIANXIANGDEYINGXIANG。

　　TU2：BENERANDEXIFURONGLIANGYUCHUSHINONGDUDEHANSHUGUANXI。

　　活性炭吸附去除苯二胺的吸附等溫線

　　XIFUDENGWENXIANDECEDINGYUBENERANXIFUDAOHUOXINGTANBIAOMIANDEGUOCHENGZUIWEIDUIYING，YOUR2ZHIJINXING。FreundlichDENGWENXIANGENGNENGMIAOSHUHUOXINGTANZAIBIAOMIANDEXIFUGUOCHENG，XIANGGUANXISHUFENBIEWEI0.988、0.979、0.958、0.996HE0.973。TONGSHI，HUOXINGTANBIAOMIANXIFUGUOCHENGWEIMOXINGMIAOSHUDEDRK，R2=0.968。CONGGAIDENGWENXIANDEDAODEXIFUNENGJUNDAYUPINGJUNZHI，YUHUAXUEXIFUXIANGDUIYING。TemkinDENGWENXIANTIGONGDEBUTONGNENGLIANGDEGUANCHABIAOMING，SUANXINGHUOXINGTANBIAOMIANDEXIFUREB1YUANYOUYULVHUAXINHUOXINGTANBIAOMIANDEXIFUREB1，ERJIEHENENGPINGHENGZEXIANGFAN;ZHEYIWEIZHUBENERANZAITEDINGHUOHUAJIDEHUOXINGTANBIAOMIANXIFUBIZAIHUOXINGTANLINSUANBIAOMIANDEXIFUGENGQIANGLIE。

　　TU3：GENJULangmuir(a)，Freundlich，(b)TIAOJIAND-R-K，(c)HETemkin，(D)BENERANZAIHUOXINGTANSHANGDEXIFUDENGWENXIAN。

　　ZAIYANJIUHUOXINGTANXIFUQUCHUBENERANZHONG，CAIYONGQITAHUOHUAJIHELINSUANZHIBEIXIFUXINGNENGJIAOHAODEHUOXINGTAN，BINGJIANGQIYINGYONGYUDUIBENERANDEHUANYUANFANYING。GENJUHUOXINGTANDECAIZHIFENXIFAXIANYONGTEDINGHUOHUAJIHUOHUADEHUOXINGTANYONGYOUDEDIANZHIHEYAJIALANXIFUZHIGENGGAO。RANER，pHZHIDELINGDIANHEDIANBIAOMINGSUOYOUZHIBEIDEHUOXINGTANDOUSHISUANXINGDE(pHPZC˂7)。FreundlichHEDubinin-RadushkevichDENGWENXIANMOXINGNENGMIAOSHUZHEXIEHUOXINGTANZAIBIAOMIANSHANGDEXIFUDONGLIXUE(R2˃0.95)，CONGGAIDENGWENXIANDEDAODEXIFUNENGJUNDAYUPINGJUNZHI，DUIYINGYUHUAXUEXIFU。

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